催化硫代-Sommelet-Hauser 重排：在合成吲哚酮中的应用。
Catalytic thia-Sommelet-Hauser rearrangement: application to the synthesis of oxindoles.
机构信息
Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing, China.
出版信息
Org Lett. 2011 Mar 4;13(5):1210-3. doi: 10.1021/ol200091k. Epub 2011 Feb 9.
PMID:21306152
Abstract
A series of 3-arylthio-1,3-disubstituted-oxindoles were prepared in good yields by the reaction of α-diazocarbonyl compounds and sulfenamides. The reaction involves a Rh-catalyzed thia-Sommelet-Hauser-type rearrangement.
摘要
通过α-重氮羰基化合物和亚磺酰胺的反应，制备了一系列收率良好的 3-芳基硫代-1,3-二取代色酮。该反应涉及 Rh 催化的噻 Sommelet-Hauser 重排。
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