铜催化的 1,3-氮唑与 N-对甲苯磺酰腙的直接苄基化或烯丙基化反应。
Copper-catalyzed direct benzylation or allylation of 1,3-azoles with N-tosylhydrazones.
机构信息
Beijing National Laboratory of Molecular Sciences, College of Chemistry, Peking University, Beijing 100871, China.
出版信息
J Am Chem Soc. 2011 Mar 16;133(10):3296-9. doi: 10.1021/ja111249p. Epub 2011 Feb 22.
PMID:21341655
Abstract
Cu-catalyzed cross-coupling of N-tosylhydrazones with 1,3-azoles leads to the direct C-H benzylation or allylation. Cu carbene migratory insertion is proposed to play the key role in this transformation.
摘要
铜催化 N-对甲苯磺酰腙与 1,3-氮唑的交叉偶联反应导致直接的 C-H 苄基化或烯丙基化。Cu 卡宾迁移插入被认为在这一转化中起关键作用。
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