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酰胺和脲基功能化的吡咯和苯并吡咯作为合成的、中性的阴离子受体。

Amide- and urea-functionalized pyrroles and benzopyrroles as synthetic, neutral anion receptors.

机构信息

Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland.

出版信息

Chem Soc Rev. 2011 May;40(5):2971-85. doi: 10.1039/c1cs15006e. Epub 2011 Mar 9.

DOI:10.1039/c1cs15006e
PMID:21387070
Abstract

This critical review is dedicated to the anion complexation chemistry of amide- and urea-functionalized (benzo)pyrroles, such as pyrroles, indoles, carbazoles, isoindoles, naphthalenodipyrroles and benzodipyrroles. It provides a comprehensive overview of these simple and neutral anion sensors from the first examples up to very recent studies. There is a discussion of a gradual progress made over time, often based on careful analysis of the properties of former generations that have subsequently led to obtaining excellent effectivities and selectivities. The influence of these species on other fields of chemistry and their applications there are also discussed (57 references).

摘要

这篇评论文章主要介绍了酰胺基和脲基功能化(苯并)吡咯,如吡咯、吲哚、咔唑、异吲哚、萘并二吡咯和苯并二吡咯的阴离子络合化学。它从最早的例子到最近的研究,全面概述了这些简单的中性阴离子传感器。本文还讨论了随着时间的推移,基于对前几代化合物性质的仔细分析而取得的渐进进展,这些化合物随后产生了优异的效力和选择性。此外,还讨论了这些化合物对其他化学领域的影响及其在这些领域的应用(57 篇参考文献)。

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Amide- and urea-functionalized pyrroles and benzopyrroles as synthetic, neutral anion receptors.酰胺和脲基功能化的吡咯和苯并吡咯作为合成的、中性的阴离子受体。
Chem Soc Rev. 2011 May;40(5):2971-85. doi: 10.1039/c1cs15006e. Epub 2011 Mar 9.
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