Iridium-catalyzed anti-diastereo- and enantioselective carbonyl (α-trifluoromethyl)allylation from the alcohol or aldehyde oxidation level.
作者信息
Gao Xin, Zhang Yong Jian, Krische Michael J
机构信息
University of Texas at Austin, Department of Chemistry and Biochemistry, 1 University Station-A5300, Austin, TX 78712-1167, USA.
出版信息
Angew Chem Int Ed Engl. 2011 Apr 26;50(18):4173-5. doi: 10.1002/anie.201008296. Epub 2011 Apr 6.
Abstract
摘要
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Iridium-catalyzed anti-diastereo- and enantioselective carbonyl (α-trifluoromethyl)allylation from the alcohol or aldehyde oxidation level.铱催化从醇或醛氧化水平进行的非对映和对映选择性羰基（α-三氟甲基）烯丙基化反应。
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