Wu Fu-Hai, Li Zheng-Zheng, Zeng Cheng-Hui, Liang Zhen-Hua, Liu Yun-Jun
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 30;66(Pt 2):m211. doi: 10.1107/S1600536810002874.
The title compound, Ru(C(14)H(12)N(2))(2)(C(18)H(14)N(4))(2)·2H(2)O, consists of an Ru(II) complex cation, two perchlorate anions and two uncoordinated water mol-ecules. The Ru(II) ion is chelated by a 10,11,12,13-tetra-hydro-dipyrido[3,2-a:2',3'-c]phenazine ligand and two 2,9-dimethyl-1,10-phenanthroline ligands in a distorted octa-hedral geometry. The two uncoord-inated water mol-ecules are disordered over five positions, with an occupancy factor of about 0.4 for each site. A supra-molecular structure is formed by weak π-π inter-actions between neighbouring mol-ecules, with centroid-centroid distances of 3.618 (2) and 3.749 (2) Å.
标题化合物Ru(C₁₄H₁₂N₂)₂(C₁₈H₁₄N₄)₂·2H₂O由一个Ru(II)配合物阳离子、两个高氯酸根阴离子和两个未配位的水分子组成。Ru(II)离子由一个10,11,12,13-四氢二吡啶并[3,2-a:2',3'-c]菲嗪配体和两个2,9-二甲基-1,10-菲咯啉配体以扭曲的八面体几何构型螯合。两个未配位的水分子在五个位置上无序分布,每个位置的占有率约为0.4。相邻分子之间通过弱的π-π相互作用形成超分子结构,质心-质心距离为3.618(2)和3.749(2) Å。