• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

双(2,9 - 二甲基 - 1,10 - 菲咯啉 - κN,N')(10,11,12,13 - 四氢 - 二吡啶并[3,2 - a:2',3'-c]吩嗪 - κN,N)钌(II)双(高氯酸盐)二水合物

Bis(2,9-dimethyl-1,10-phenanthroline-κN,N')(10,11,12,13-tetra-hydro-dipyrido[3,2-a:2',3'-c]phenazine-κN,N)ruthenium(II) bis-(perchlorate) dihydrate.

作者信息

Wu Fu-Hai, Li Zheng-Zheng, Zeng Cheng-Hui, Liang Zhen-Hua, Liu Yun-Jun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 30;66(Pt 2):m211. doi: 10.1107/S1600536810002874.

DOI:10.1107/S1600536810002874
PMID:21579673
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2979898/
Abstract

The title compound, Ru(C(14)H(12)N(2))(2)(C(18)H(14)N(4))(2)·2H(2)O, consists of an Ru(II) complex cation, two perchlorate anions and two uncoordinated water mol-ecules. The Ru(II) ion is chelated by a 10,11,12,13-tetra-hydro-dipyrido[3,2-a:2',3'-c]phenazine ligand and two 2,9-dimethyl-1,10-phenanthroline ligands in a distorted octa-hedral geometry. The two uncoord-inated water mol-ecules are disordered over five positions, with an occupancy factor of about 0.4 for each site. A supra-molecular structure is formed by weak π-π inter-actions between neighbouring mol-ecules, with centroid-centroid distances of 3.618 (2) and 3.749 (2) Å.

摘要

标题化合物Ru(C₁₄H₁₂N₂)₂(C₁₈H₁₄N₄)₂·2H₂O由一个Ru(II)配合物阳离子、两个高氯酸根阴离子和两个未配位的水分子组成。Ru(II)离子由一个10,11,12,13-四氢二吡啶并[3,2-a:2',3'-c]菲嗪配体和两个2,9-二甲基-1,10-菲咯啉配体以扭曲的八面体几何构型螯合。两个未配位的水分子在五个位置上无序分布,每个位置的占有率约为0.4。相邻分子之间通过弱的π-π相互作用形成超分子结构,质心-质心距离为3.618(2)和3.749(2) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c731/2979898/3c0fabf1b55f/e-66-0m211-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c731/2979898/0cc36c810505/e-66-0m211-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c731/2979898/a8bf33432ef0/e-66-0m211-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c731/2979898/3c0fabf1b55f/e-66-0m211-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c731/2979898/0cc36c810505/e-66-0m211-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c731/2979898/a8bf33432ef0/e-66-0m211-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c731/2979898/3c0fabf1b55f/e-66-0m211-fig3.jpg

相似文献

1
Bis(2,9-dimethyl-1,10-phenanthroline-κN,N')(10,11,12,13-tetra-hydro-dipyrido[3,2-a:2',3'-c]phenazine-κN,N)ruthenium(II) bis-(perchlorate) dihydrate.双(2,9 - 二甲基 - 1,10 - 菲咯啉 - κN,N')(10,11,12,13 - 四氢 - 二吡啶并[3,2 - a:2',3'-c]吩嗪 - κN,N)钌(II)双(高氯酸盐)二水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 30;66(Pt 2):m211. doi: 10.1107/S1600536810002874.
2
Bis[bis-(4,4'-dimethyl-2,2'-bipyridine)(10,11,12,13-tetra-hydro-dipyrido[3,2-a:2',3'-c]phenazine)ruthenium(II)] tetra-kis(perchlorate) acetonitrile disolvate monohydrate.双[双-(4,4'-二甲基-2,2'-联吡啶)(10,11,12,13-四氢-二吡啶并[3,2-a:2',3'-c]吩嗪)钌(II)]高氯酸盐四水合物乙腈二溶剂合物一水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 21;66(Pt 5):m552-3. doi: 10.1107/S1600536810014005.
3
Aqua-(3-hydroxy-benzoato-κO)bis-(1,10-phenanthroline-κN,N')cobalt(II) 3-hydroxy-benzoate penta-hydrate.水合(3-羟基苯甲酸根-κO)双(1,10-菲咯啉-κN,N')钴(II)3-羟基苯甲酸盐五水合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 23;64(Pt 2):m382-3. doi: 10.1107/S1600536808001815.
4
(Carbonato-κO,O')bis-(1,10-phenan-throline-κN,N')cobalt(III) nitrate monohydrate.硝酸一水合(碳酸根 - κO,O')双 -(1,10 - 菲咯啉 - κN,N')钴(III)
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):m46-7. doi: 10.1107/S1600536809052763.
5
catena-Poly[[[tetra-aqua-cobalt(II)]-μ-4,4'-bipyridine-κN:N'] bis-(perchlorate) 4,4'-bipyridine disolvate dihydrate].链状聚[[[四水合钴(II)]-μ-4,4'-联吡啶-κN:N']双(高氯酸盐)4,4'-联吡啶二溶剂合物二水合物]
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 31;64(Pt 11):m1485. doi: 10.1107/S1600536808035125.
6
Bis(benzoato-κO,O')(2,9-dimethyl-1,10-phenanthroline-κN,N')cobalt(II).双(苯甲酸根-κO,O')(2,9-二甲基-1,10-菲咯啉-κN,N')钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 9;64(Pt 2):m327. doi: 10.1107/S1600536807068080.
7
[Malonato(2-)-κO,O']bis-(1,10-phenanthroline-κN,N')zinc(II) penta-hydrate.[丙二酸根(2-)-κO,O']双-(1,10-菲咯啉-κN,N')锌(II)五水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 11;67(Pt 1):m66-7. doi: 10.1107/S1600536810049573.
8
Aqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')bis-(2-hydroxy-benzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate.水合 -(2,9 - 二甲基 - 1,10 - 菲咯啉 - κN,N')双 -(2 - 羟基苯甲酸根 - κO)锰(II)2,9 - 二甲基 - 1,10 - 菲咯啉半溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 14;65(Pt 2):m194-5. doi: 10.1107/S1600536809000981.
9
Tris(1,10-phenanthroline-κN,N')nickel(II) dinitrate tetra-hydrate.硝酸双(1,10-菲咯啉-κN,N')合镍(II)四水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1794-5. doi: 10.1107/S160053681104880X. Epub 2011 Nov 23.
10
Aqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')bis-(3-hydroxy-benzoato-κO)manganese(II)-2,9-dimethyl-1,10-phenanthroline-water (1/1/1).水合 -(2,9 - 二甲基 - 1,10 - 菲咯啉 - κN,N')双 -(3 - 羟基苯甲酸根 - κO)锰(II)- 2,9 - 二甲基 - 1,10 - 菲咯啉 - 水(1/1/1)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m901. doi: 10.1107/S1600536809025926.

本文引用的文献

1
Pharmacological Effects of the Ruthenium Complex NAMI-A Given Orally to CBA Mice With MCa Mammary Carcinoma.口服钌配合物NAMI - A对患有MCa乳腺癌的CBA小鼠的药理作用。
Met Based Drugs. 2001;8(1):1-7. doi: 10.1155/MBD.2001.1.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Mechanism of the hydrogenation of ketones catalyzed by trans-dihydrido(diamine)ruthenium II complexes.反式二氢(二胺)钌II配合物催化酮氢化反应的机理
J Am Chem Soc. 2002 Dec 18;124(50):15104-18. doi: 10.1021/ja016817p.
4
Blood concentration and toxicity of the antimetastasis agent NAMI-A following repeated intravenous treatment in mice.抗转移剂NAMI-A在小鼠反复静脉注射治疗后的血药浓度及毒性
Pharmacol Toxicol. 2000 Nov;87(5):193-7. doi: 10.1034/j.1600-0773.2000.d01-73.x.