（E）-N'-[（2-羟基-1-萘基）亚甲基]苯甲酰肼一水合物
(E)-N'-[(2-Hydroxy-1-naphthyl)methyl-ene]benzohydrazide monohydrate.
作者信息
Qiao Yan, Ju Xiuping, Gao Zhiqing, Kong Lingqian
机构信息
Dongchang College, Liaocheng University, Liaocheng, 250059, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 9;66(Pt 1):o95. doi: 10.1107/S160053680905212X.
In the title compound, C(18)H(14)N(2)O(2)·H(2)O, the dihedral angle between the benzene ring and the naphthalene system is 5.18 (10)°. Intra-molecular N-H⋯O hydrogen bonds influence the molecular conformation. In the crystal, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds are observed as well as π-π inter-actions between the phenyl ring and the substituted ring of the naphthalene [centroid-centroid distance = 3.676 (11) Å].
在标题化合物C₁₈H₁₄N₂O₂·H₂O中，苯环与萘环体系之间的二面角为5.18 (10)°。分子内N—H⋯O氢键影响分子构象。在晶体中，观察到分子间的N—H⋯O和O—H⋯O氢键以及苯环与萘的取代环之间的π - π相互作用[质心 - 质心距离 = 3.676 (11) Å]。
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