（苯甲酮亚胺-κN）-氯代（氢化三吡唑基硼酸根）-（三苯基膦）钌（II）二乙醚溶剂合物
(Benzophenone imine-κN)-chlorido(hydrido-tripyrazolyl-borato)-(triphenyl-phosphine)ruthenium(II) diethyl ether solvate.
作者信息
Tong Hung-Chun, Hsu Chih-Yung Chen, Lo Yih-Hsing, Lin Chia-Her, Wang Yu
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 22;64(Pt 11):m1453. doi: 10.1107/S1600536808033722.
The reaction of RuCl(Tp)(Ph(3)P)(2), where Tp is (CH)(3)N(2)BH, with benzophenone imine leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(13)H(11)N)(C(18)H(15)P)]·C(4)H(10)O. The environment about the Ru atom corresponds to a slightly distorted octa-hedron and the bite angle of the Tp ligand produces an average N-Ru-N angle of 86.3 (9)°. The three Ru-N(Tp) bond lengths [2.117 (2), 2.079 (2) and 2.084 (2) Å] are slightly longer than the average distance (2.038 Å) in other ruthenium-Tp complexes.
RuCl(Tp)(Ph(3)P)(2)（其中Tp为(CH)(3)N(2)BH）与二苯甲酮亚胺反应生成标题化合物[Ru(C(9)H(10)BN(6))Cl(C(13)H(11)N)(C(18)H(15)P)]·C(4)H(10)O。Ru原子周围的环境对应一个稍有畸变的八面体，Tp配体的咬角产生的平均N-Ru-N角为86.3 (9)°。三条Ru-N(Tp)键长[2.117 (2)、2.079 (2)和2.084 (2) Å]略长于其他钌-Tp配合物中的平均距离(2.038 Å)。
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