Lin Chia-Her, Kuo Ting-Shen, Tong Hung-Chun, Chen Hsu Chih-Yung, Lo Yih-Hsing
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):m1511-2. doi: 10.1107/S1600536808036039.
The reaction of [RuCl(C(9)H(10)BN(6))(C(18)H(15)P)(2)] with benzo-phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(N(3))(HN=CPh(2))(C(18)H(15)P)]·C(4)H(10)O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenyl-phosphine ligand, one N atom of the azide anion and one N atom of the benzophenone-imine ligand in a slightly distorted octa-hedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru-N-N angle of 125.9 (3)°. There is a small difference between the N-N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom.
在叠氮化钠存在下，[RuCl(C₉H₁₀BN₆)(C₁₈H₁₅P)₂]与二苯甲酮亚胺在甲醇中反应，生成标题化合物[Ru(C₉H₁₀BN₆)(N₃)(HN = CPh₂)(C₁₈H₁₅P)]·C₄H₁₀O，它以二乙醚溶剂化物形式结晶。在晶体结构中，Ru原子由一个氢化三(吡唑基)硼酸根阴离子的三个N原子、一个三苯基膦配体的一个P原子、一个叠氮阴离子的一个N原子和一个二苯甲酮亚胺配体的一个N原子以稍有畸变的八面体几何构型配位。叠氮阴离子几乎呈直线型[177.0 (5)°]，Ru - N - N角为125.9 (3)°。N - N距离[1.200 (5) 和1.164 (5) Å]之间存在微小差异，较长的键与Ru原子相邻。
