（苯甲腈-κN）氯代[氢三（吡唑-1-基-κN）硼酸盐]（三苯基膦-κP）钌（II）乙醇溶剂化物
(Benzonitrile-κN)chlorido[hydrido-tris(pyrazol-1-yl-κN)borato](triphenyl-phosphine-κP)ruthenium(II) ethanol solvate.
作者信息
Tong Hung-Chun, Hung Yu-Chen, Wang Po-Yo, Lin Chia-Her, Lo Yih-Hsing
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m438. doi: 10.1107/S1600536809010265.
Abstract
The reaction of [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(2)] with benzo-nitrile leads to crystals of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(C(7)H(5)N)]·C(2)H(5)OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa-hedron with an average N-Ru-N bite angle of the Tp ligand of 86.6 (2)°.
摘要
[Ru(C₉H₁₀BN₆)Cl(C₁₈H₁₅P)₂]与苯甲腈反应生成标题化合物[Ru(C₉H₁₀BN₆)Cl(C₁₈H₁₅P)(C₇H₅N)]·C₂H₅OH的晶体。在晶体结构中，钌金属中心周围的环境对应于一个略有扭曲的八面体，Tp配体的平均N-Ru-N夹角为86.6 (2)°。
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