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双(1,10-菲咯啉-κN,N')(苯乙酸根-κO)铜(II)苯乙酸六水合物

Bis(1,10-phenanthroline-κN,N')(phenyl-acetato-κO)copper(II) phenyl-acetate hexa-hydrate.

作者信息

Tu Bing-Tian, Xie Hong-Zhen, Ren Ying-Tao, Chen Jing-Zhong

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 31;64(Pt 11):m1475. doi: 10.1107/S1600536808032480.

Abstract

In the title compound, Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water mol-ecules are inter-connected by hydrogen bonds, completing dodeca-water (H(2)O)(12) clusters which are hydrogen bonded to the carboxyl-ate groups of phenyl-acetate anions, building up one-dimensional anionic chains propagating along [100]. Between the cationic and anionic chains are hydrogen bonds from water mol-ecules to the carboxyl-ate O atoms belonging to the phenyl-acetato ligands.

摘要

在标题化合物Cu(C₈H₇O₂)(C₁₂H₈N₂)₂·6H₂O中,铜原子处于扭曲的四方锥配位环境中。六个晶体学独立的未配位水分子通过氢键相互连接,形成十二水(H₂O)₁₂簇,这些簇通过氢键与苯乙酸根阴离子的羧酸根基团相连,形成沿[100]方向延伸的一维阴离子链。在阳离子链和阴离子链之间存在水分子与属于苯乙酸根配体的羧酸根O原子之间的氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b74/2959544/f5f8672e8cb8/e-64-m1475-fig1.jpg

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