Jing Buqin, Li Lianzhi, Dong Jianfang, Xu Tao
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m464. doi: 10.1107/S1600536811009676. Epub 2011 Mar 19.
In the title complex, Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)·7H(2)O, the central Cu(II) ion is five coordinate, being bound to four N atoms from two 1,10-phenanthroline ligands and one O atom from an acetate anion in a strongly distorted square-pyramidal configuration. Hydrogen-bonded water mol-ecules and an uncoordinated acetate anion form a two-dimensional polymeric structure parallel to (010). The cations are linked to this layer via O-H⋯O hydrogen bonds between one of the water mol-ecules and the coordinated acetate anion.
在标题配合物Cu(CH₃CO₂)(C₁₂H₈N₂)₂·7H₂O中,中心Cu(II)离子为五配位,以严重扭曲的四方锥构型与两个1,10 - 菲咯啉配体的四个N原子和一个乙酸根阴离子的一个O原子相连。氢键连接的水分子和一个未配位的乙酸根阴离子形成了一个平行于(010)的二维聚合结构。阳离子通过一个水分子与配位的乙酸根阴离子之间的O—H⋯O氢键与该层相连。