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二氯（6,6'-二甲基-2,2'-联吡啶-κN,N'）镉（II）

Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κN,N')cadmium(II).

作者信息

Alizadeh Robabeh, Mohammadi Eshlaghi Parisa, Amani Vahid

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 31;66(Pt 8):m1024. doi: 10.1107/S1600536810029399.

DOI:10.1107/S1600536810029399
PMID:21588099
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3007525/
Abstract

In the title compound, [CdCl(2)(C(12)H(12)N(2))], the Cd(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6,6'-dimethyl-2,2'-bipyridine ligand and two terminal Cl atoms. Inter-molecular C-H⋯Cl hydrogen bonds and π-π stacking inter-actions between the pyridyl rings [centroid-centroid distance = 3.7337 (18) Å] are present in the crystal structure.

摘要

在标题化合物[CdCl₂(C₁₂H₁₂N₂)]中，Cd(II)原子由一个6,6'-二甲基-2,2'-联吡啶配体的两个N原子和两个端基Cl原子以扭曲的四面体几何构型进行四配位。晶体结构中存在分子间C—H⋯Cl氢键以及吡啶环之间的π-π堆积相互作用[质心-质心距离 = 3.7337 (18) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2b1/3007525/8ed987573c0d/e-66-m1024-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2b1/3007525/7d4b1bf01a4b/e-66-m1024-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2b1/3007525/8ed987573c0d/e-66-m1024-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2b1/3007525/7d4b1bf01a4b/e-66-m1024-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2b1/3007525/8ed987573c0d/e-66-m1024-fig2.jpg

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