二溴（6,6'-二甲基-2,2'-联吡啶-κ(2)N,N'）镉
Dibromido(6,6'-dimethyl-2,2'-bipyridine-κ(2)N,N')cadmium.
作者信息
Shirvan Sadif A, Haydari Dezfuli Sara
机构信息
Department of Chemistry, Islamic Azad University, Omidieh Branch, Omidieh, Iran.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1143. doi: 10.1107/S1600536812033648. Epub 2012 Aug 4.
Abstract
In the title compound, [CdBr(2)(C(12)H(12)N(2))], the Cd(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6,6'-dimethyl-2,2'-bipyridine ligand and two terminal Br atoms. In the crystal, C-H⋯Br hydrogen bonds and π-π stacking inter-actions between the pyridine rings [centroid-centroid distance = 3.763 (5) Å] are present.
摘要
在标题化合物[CdBr₂(C₁₂H₁₂N₂)]中，Cd(II)原子由一个6,6'-二甲基-2,2'-联吡啶配体的两个N原子和两个末端Br原子以扭曲的四面体几何构型进行四配位。在晶体中，存在C—H⋯Br氢键以及吡啶环之间的π-π堆积相互作用[质心-质心距离 = 3.763 (5) Å]。
Zotero 插件