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二溴（6,6'-二甲基-2,2'-联吡啶-κN,N'）锌（II）

Dibromido(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

作者信息

Alizadeh Robabeh, Khoshtarkib Zeinab, Chegeni Katayoon, Ebadi Amin, Amani Vahid

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 7;65(Pt 11):m1311. doi: 10.1107/S1600536809039610.

DOI:10.1107/S1600536809039610
PMID:21578074
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2971289/
Abstract

In the title compound, [ZnBr(2)(C(12)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral arrangement by an N,N'-bidentate 6,6'-dimethyl-2,2'-bipyridine ligand and two bromide ions. In the crystal, there are aromatic π-π contacts between the pyridine rings [centroid-centroid distances = 3.818 (3) and 3.728 (4) Å].

摘要

在标题化合物[ZnBr₂(C₁₂H₁₂N₂)]中，Zn(II)原子通过一个N,N'-双齿的6,6'-二甲基-2,2'-联吡啶配体和两个溴离子以扭曲的四面体构型进行四配位。在晶体中，吡啶环之间存在芳香π-π接触[质心-质心距离 = 3.818 (3) 和3.728 (4) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7468/2971289/29105a678067/e-65-m1311-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7468/2971289/d18beee1e286/e-65-m1311-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7468/2971289/29105a678067/e-65-m1311-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7468/2971289/d18beee1e286/e-65-m1311-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7468/2971289/29105a678067/e-65-m1311-fig2.jpg

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