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Highly stereoselective Brønsted acid catalyzed synthesis of spirooxindole pyrans.高对映选择性布朗斯台德酸催化的螺环吲哚吡喃合成。
Org Lett. 2011 Jun 17;13(12):3086-9. doi: 10.1021/ol200987c. Epub 2011 May 18.
2
Stereoselective synthesis of spirooxindoles by palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with isatins.钯催化γ-亚甲基-δ-戊内酯与异吲哚酮的脱羧环化反应立体选择性合成螺环氧化吲哚
Org Lett. 2009 Aug 20;11(16):3754-6. doi: 10.1021/ol901348f.
3
Titanium-catalyzed stereoselective synthesis of spirooxindole oxazolines.钛催化的螺环吲哚恶唑啉的立体选择性合成。
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4
Stereoselective synthesis of five-membered spirooxindoles through Tomita zipper cyclization.通过 Tomita 拉链环化反应立体选择性合成五元稠合螺环氧化吲哚。
Org Lett. 2013 Sep 20;15(18):4714-7. doi: 10.1021/ol4020305. Epub 2013 Sep 9.
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Multicomponent reaction discovery: three-component synthesis of spirooxindoles.多组分反应发现：螺环氧化吲哚的三组分合成。
Org Lett. 2010 Feb 5;12(3):572-5. doi: 10.1021/ol902764k.
6
Stereoselective synthesis of spirocyclic oxindoles via Prins cyclizations.通过普林斯环化反应立体选择性合成螺环氧化吲哚。
Org Lett. 2009 Aug 6;11(15):3362-5. doi: 10.1021/ol901201k.
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Catalytic stereoselective synthesis of diverse oxindoles and spirooxindoles from isatins.从靛红出发，通过催化立体选择性合成多种吲哚酮和螺吲哚酮。
ACS Comb Sci. 2012 Apr 9;14(4):285-93. doi: 10.1021/co300003c. Epub 2012 Apr 2.
8
Three-component synthesis of spiro[indoline-3,4'-pyrano[3,2-b]pyran]- 2,8'-diones using a one-pot reaction.采用一锅法反应合成螺[吲哚啉-3,4'-吡喃并[3,2-b]吡喃]-2,8'-二酮的三组分合成
Comb Chem High Throughput Screen. 2014 Feb;17(2):132-40. doi: 10.2174/13862073113166660067.
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FeCl3-catalyzed stereoselective construction of spirooxindole tetrahydroquinolines via tandem 1,5-hydride transfer/ring closure.FeCl3 催化的通过串联 1,5-氢转移/环化反应构建螺环氧化吲哚四氢喹啉的立体选择性方法。
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Synthesis of oxacyclic scaffolds via dual ruthenium hydride/Brønsted acid-catalyzed isomerization/cyclization of allylic ethers.通过双氢化钌/布朗斯特酸催化的烯丙基醚异构化/环化反应合成含氧杂环骨架。
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An Enantioselective Cross-Dehydrogenative Coupling Catalysis Approach to Substituted Tetrahydropyrans.对取代的四氢吡喃的对映选择性交叉脱氢偶联催化方法。
J Am Chem Soc. 2018 May 23;140(20):6212-6216. doi: 10.1021/jacs.8b03063. Epub 2018 May 10.
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A Biocatalytic Route to Highly Enantioenriched β-Hydroxydioxinones.一条通往高对映体富集的β-羟基二氧杂环己酮的生物催化途径。
Adv Synth Catal. 2017 Apr 3;359(7):1131-1137. doi: 10.1002/adsc.201700095. Epub 2017 Mar 2.
3
Molecular diversity of spirooxindoles. Synthesis and biological activity.螺环氧化吲哚的分子多样性。合成与生物活性。
Mol Divers. 2016 Feb;20(1):299-344. doi: 10.1007/s11030-015-9629-8. Epub 2015 Sep 29.
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Catalytic enantioselective synthesis of 2-aryl-chromenes.2-芳基色烯的催化对映选择性合成
Chem Sci. 2014 Jun;5(6):2277-2281. doi: 10.1039/C4SC00423J.
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Highly Efficient and Stereoselective Construction of Bispirooxindole Derivatives via a Three-Component 1,3-Dipolar Cycloaddition Reaction.高立体选择性地构建双螺环氧化吲哚衍生物的三组分 1,3-偶极环加成反应。
ChemistryOpen. 2014 Jun;3(3):93-8. doi: 10.1002/open.201402003. Epub 2014 Jun 18.
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Asymmetric Aldol Reaction of 3-Acetyl-2-chromen-2-ones and Isatins Catalyzed by a Bifunctional Quinidine Urea Catalyst.双功能奎宁定脲催化剂催化3-乙酰基-2-色满-2-酮与异吲哚酮的不对称羟醛反应
Adv Synth Catal. 2014 Jan 13;356(1):237-241. doi: 10.1002/adsc.201300623.
7
An N-heterocyclic carbene/Lewis acid strategy for the stereoselective synthesis of spirooxindole lactones.N-杂环卡宾/路易斯酸策略用于立体选择性合成螺[吲哚啉-2,3’-吡咯烷]-2,5-二酮。
Angew Chem Int Ed Engl. 2012 May 14;51(20):4963-7. doi: 10.1002/anie.201201643. Epub 2012 Apr 4.
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Enantioselective Pictet-Spengler Reactions of Isatins for the Synthesis of Spiroindolones.用于合成螺吲哚酮的异吲哚酮的对映选择性 Pictet-Spengler 反应
Tetrahedron Lett. 2011 Oct 26;52(43):5550-5553. doi: 10.1016/j.tetlet.2011.08.071.
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Bi(OTf)3-, TfOH-, and TMSOTf-mediated, one-pot epoxide rearrangement, addition, and intramolecular silyl-modified Sakurai (ISMS) cascade toward dihydropyrans: comparison of catalysts and role of Bi(OTf)3.三氟甲磺酸铟（Bi(OTf)3）、三氟甲磺酸（TfOH）和三甲基硅基三氟甲磺酸酯（TMSOTf）介导的一锅法环氧化物重排、加成和分子内硅基化 Sakurai（ISMS）级联反应制备二氢吡喃：催化剂的比较和 Bi(OTf)3 的作用。
J Org Chem. 2011 Nov 18;76(22):9269-77. doi: 10.1021/jo201478d. Epub 2011 Oct 25.
本文引用的文献
1
Concise syntheses of the abyssinones and discovery of new inhibitors of prostate cancer and MMP-2 expression.阿比西酮的简洁合成以及前列腺癌和基质金属蛋白酶-2表达新抑制剂的发现。
ACS Med Chem Lett. 2010 Nov 11;1(8):400-405. doi: 10.1021/ml100110x.
2
Prins-type macrocyclizations as an efficient ring-closing strategy in natural product synthesis.普林斯型大环化反应作为一种有效的环闭策略在天然产物合成中的应用。
Angew Chem Int Ed Engl. 2010 Nov 2;49(45):8316-26. doi: 10.1002/anie.201002809.
3
Stereochemical surprises in the Lewis acid-mediated allylation of isatins.路易斯酸促进的色酮烯丙基化反应中的立体化学意外。
J Org Chem. 2010 Oct 1;75(19):6720-3. doi: 10.1021/jo101420e.
4
A rapid three-component MgI(2)-mediated synthesis of 3,3-pyrollidinyl spirooxindoles.一种快速的三组分 MgI(2)-介导的 3,3-吡咯烷基螺[吲哚啉-2,3'-氧杂吲哚]的合成方法。
J Org Chem. 2010 Oct 1;75(19):6693-5. doi: 10.1021/jo101077g.
5
Organocatalytic synthesis of spiro compounds via a cascade Michael-Michael-aldol reaction.通过串联迈克尔-迈克尔-羟醛缩合反应的有机催化合成螺化合物。
Chem Commun (Camb). 2010 Oct 7;46(37):6953-5. doi: 10.1039/c0cc01522a. Epub 2010 Aug 23.
6
Novel, one-pot, three-component route to indol-3-yl substituted spirooxindole derivatives.新型的、一锅法、三组分合成吲哚-3-基取代螺环氧化吲哚衍生物的路线。
J Comb Chem. 2010 Sep 13;12(5):659-63. doi: 10.1021/cc100064c.
7
Mechanistic investigation of the palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with isocyanates: kinetic studies and origin of the site selectivity in the nucleophilic attack at a (pi-allyl)palladium.钯催化γ-亚甲基-δ-戊内酯与异氰酸酯的脱羧环化反应的机理研究：动力学研究及（π-烯丙基）钯中亲核进攻的位点选择性的起源。
J Am Chem Soc. 2010 Jun 2;132(21):7508-13. doi: 10.1021/ja1023223.
8
Multicomponent reaction discovery: three-component synthesis of spirooxindoles.多组分反应发现：螺环氧化吲哚的三组分合成。
Org Lett. 2010 Feb 5;12(3):572-5. doi: 10.1021/ol902764k.
9
Catalytic asymmetric synthesis of substituted 3-hydroxy-2-oxindoles.取代3-羟基-2-吲哚酮的催化不对称合成。
Angew Chem Int Ed Engl. 2010;49(4):744-7. doi: 10.1002/anie.200904393.
10
Total synthesis of aigialomycin D using a one-pot ketene generation-trapping-aromatization sequence.使用一锅法烯酮生成-捕获-芳构化序列全合成艾氏霉素D。
Org Lett. 2009 Nov 5;11(21):4910-3. doi: 10.1021/ol901979x.
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