融合两个世界的精华：用于对映选择性催化的人工金属酶。
Merging the best of two worlds: artificial metalloenzymes for enantioselective catalysis.
机构信息
Department of Chemistry, University of Basel, Spitalstrasse 51, CH-4056 Basel, Switzerland.
出版信息
Chem Commun (Camb). 2011 Aug 14;47(30):8470-6. doi: 10.1039/c1cc11592h. Epub 2011 May 20.
PMID:21603692
Abstract
Artificial metalloenzymes result from combining a catalytically active organometallic moiety with a macromolecular host. The resulting hybrid catalysts combine attractive features of both homogeneous and enzymatic systems. Herein we summarize the recent progress in this emerging field and outline the challenges ahead.
摘要
人工金属酶是将催化活性的有机金属部分与大分子宿主结合而成的。所得的杂化催化剂结合了均相和酶系统的吸引人的特点。本文总结了这一新兴领域的最新进展，并概述了未来的挑战。
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