钯催化的芳基胺与炔烃的 Sonogashira 反应通过芳基重氮盐的原位形成。
Palladium-catalyzed Sonogashira reactions of aryl amines with alkynes via in situ formation of arenediazonium salts.
机构信息
Leibniz-Institut für Katalyse e.V. an der Universitüt Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
出版信息
Chem Commun (Camb). 2011 Jul 28;47(28):7959-61. doi: 10.1039/c1cc12552d. Epub 2011 Jun 24.
PMID:21706078
Abstract
A general and convenient palladium-catalyzed Sonogashira reaction of in situ generated arenediazonium salts has been developed and various internal arylalkynes are produced in good yields under mild conditions.
摘要
一种通用且方便的钯催化原位生成的芳基重氮盐的 Sonogashira 反应已被开发出来，在温和条件下可以高产率得到各种内部芳基炔烃。
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