链状聚[[[4,6-双-(2-吡啶基)-1,3,5-三嗪-2-醇根合]铜(II)]-μ-氯]
catena-Poly[[[4,6-bis-(2-pyrid-yl)-1,3,5-triazin-2-olato]copper(II)]-μ-chlorido].
作者信息
Cao Man-Li
机构信息
Department of Chemistry, Guangdong University of Education, Guangzhou 510303, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m739. doi: 10.1107/S1600536811016989. Epub 2011 May 11.
Abstract
The title compound, Cu(C(13)H(8)N(5)O)Cl, has a chain structure parallel to [100] with Cu(2+) cations in a trigonal-bipyramidal coordination environment. The ligand adopts a tridentate tripyridyl coordination mode and a chloride ion acts as a bridge. The chains are linked via weak C-H⋯O and C-H⋯Cl hydrogen bonds into a three-dimensional supra-molecular network.
摘要
标题化合物[Cu(C₁₃H₈N₅O)Cl]ₙ具有平行于[100]的链状结构，Cu²⁺阳离子处于三角双锥配位环境中。配体采用三齿三吡啶配位模式，氯离子作为桥连原子。这些链通过弱的C-H⋯O和C-H⋯Cl氢键连接成三维超分子网络。
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