Department of Chemistry, Binghamton University, Binghamton, NY 13902, USA.
Molecules. 2011 Jul 18;16(7):5963-74. doi: 10.3390/molecules16075963.
Ionic liquids are obvious candidates for use in electrochemical applications due to their ionic character. Nevertheless, relatively little has been done to explore their application in electrosynthesis. We have studied the Shono oxidation of arylamines and carbamates using ionic liquids as recyclable solvents and have noted that the viscosity of the medium is a major problem, although with the addition of sufficient co-solvent, good results and excellent recovery and recycling of the ionic liquid can be achieved.
离子液体由于其离子特性，是电化学应用中很有前途的候选物质。然而，人们对它们在电合成中的应用的研究相对较少。我们研究了芳胺和氨基甲酸酯的 Shono 氧化反应，使用离子液体作为可回收的溶剂，并注意到介质的粘度是一个主要问题，尽管加入足够的共溶剂，可以获得良好的结果和离子液体的优异回收和再循环。
