Nakano Takahiro, Sugimoto Sachiko, Matsunami Katsuyoshi, Otsuka Hideaki
Department of Pharmacognosy, Graduate School of Biomedical Sciences, Hiroshima University, Japan.
Chem Pharm Bull (Tokyo). 2011;59(9):1141-8. doi: 10.1248/cpb.59.1141.
From aerial parts of Dianthus japonicus, six new and seven known oleanane-type triterpene saponins were isolated. The structures of the new saponins, named dianthosaponins A-F, were elucidated by means of high resolution mass spectrometry, and extensive inspection of one- and two-dimensional NMR spectroscopic data. A new C-glycosyl flavone, a glycosidic derivative of anthranilic acid amide and a maltol glucoside were also isolated.
从日本石竹的地上部分分离出6个新的和7个已知的齐墩果烷型三萜皂苷。通过高分辨率质谱以及对一维和二维核磁共振光谱数据的广泛分析,阐明了新皂苷(命名为石竹皂苷A - F)的结构。还分离出一种新的C - 糖基黄酮、邻氨基苯甲酸酰胺的糖苷衍生物和一种麦芽酚葡萄糖苷。