Department of Chemistry and the Materials Science Institute, 1253University of Oregon, Eugene, OR 97403-1253, USA.
Chem Soc Rev. 2012 Feb 7;41(3):1019-30. doi: 10.1039/c1cs15216e. Epub 2011 Sep 22.
This tutorial review surveys the wide variety of oligomeric hydroxide structures formed from aluminum, gallium, and indium. Both inorganic and ligand-supported structures are reviewed, providing a leading introduction to this research area. In addition to homometallic clusters comprising only one metal type, a series of heterometallic structures are described. This review highlights the synthesis and characterization of these nanoscale cluster compounds that have implications in a variety of fields, including catalysis, mineral mimicry, environmental chemistry, geochemistry, materials science, and semiconductors.
本教程综述了铝、镓和铟形成的各种低聚氢氧化物结构。综述了无机和配体支持的结构，为该研究领域提供了主要介绍。除了仅包含一种金属类型的同核簇外，还描述了一系列杂核结构。本综述重点介绍了这些纳米级簇化合物的合成和表征，这些化合物在催化、矿物模拟、环境化学、地球化学、材料科学和半导体等多个领域具有重要意义。
