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自猝灭缺陷玻璃在胶体向列相液晶复合材料中。

A self-quenched defect glass in a colloid-nematic liquid crystal composite.

机构信息

Scottish Universities Physics Alliance and School of Physics and Astronomy, The University of Edinburgh, James Clerk Maxwell Building, Kings Buildings, Mayfield Road, Edinburgh, EH9 3JZ, UK.

出版信息

Science. 2011 Oct 7;334(6052):79-83. doi: 10.1126/science.1209997.

Abstract

Colloidal particles immersed in liquid crystals frustrate orientational order. This generates defect lines known as disclinations. At the core of these defects, the orientational order drops sharply. We have discovered a class of soft solids, with shear moduli up to 10(4) pascals, containing high concentrations of colloidal particles (volume fraction φ ≳ 20%) directly dispersed into a nematic liquid crystal. Confocal microscopy and computer simulations show that the mechanical strength derives from a percolated network of defect lines entangled with the particles in three dimensions. Such a "self-quenched glass" of defect lines and particles can be considered a self-organized analog of the "vortex glass" state in type II superconductors.

摘要

胶体粒子沉浸在液晶中会阻碍取向有序。这会产生被称为挠曲的缺陷线。在这些缺陷的核心,取向有序急剧下降。我们发现了一类软固体,其剪切模量高达 10^4 帕斯卡,其中含有高浓度的胶体粒子(体积分数φ≳20%)直接分散到向列液晶中。共焦显微镜和计算机模拟表明,机械强度源于缺陷线的渗流网络与粒子在三维空间中的缠结。这样一种由缺陷线和粒子组成的“自淬火玻璃”可以被认为是 II 型超导体中“涡旋玻璃”状态的自组织类似物。

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