Scottish Universities Physics Alliance and School of Physics and Astronomy, The University of Edinburgh, James Clerk Maxwell Building, Kings Buildings, Mayfield Road, Edinburgh, EH9 3JZ, UK.
Science. 2011 Oct 7;334(6052):79-83. doi: 10.1126/science.1209997.
Colloidal particles immersed in liquid crystals frustrate orientational order. This generates defect lines known as disclinations. At the core of these defects, the orientational order drops sharply. We have discovered a class of soft solids, with shear moduli up to 10(4) pascals, containing high concentrations of colloidal particles (volume fraction φ ≳ 20%) directly dispersed into a nematic liquid crystal. Confocal microscopy and computer simulations show that the mechanical strength derives from a percolated network of defect lines entangled with the particles in three dimensions. Such a "self-quenched glass" of defect lines and particles can be considered a self-organized analog of the "vortex glass" state in type II superconductors.
胶体粒子沉浸在液晶中会阻碍取向有序。这会产生被称为挠曲的缺陷线。在这些缺陷的核心,取向有序急剧下降。我们发现了一类软固体,其剪切模量高达 10^4 帕斯卡,其中含有高浓度的胶体粒子(体积分数φ≳20%)直接分散到向列液晶中。共焦显微镜和计算机模拟表明,机械强度源于缺陷线的渗流网络与粒子在三维空间中的缠结。这样一种由缺陷线和粒子组成的“自淬火玻璃”可以被认为是 II 型超导体中“涡旋玻璃”状态的自组织类似物。