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（4-溴-2-{[2-(吗啉-4-基)乙基-亚氨基]-甲基}苯酚根）二氧钒（V）

(4-Bromo-2-{[2-(morpholin-4-yl)ethyl-imino]-meth-yl}phenolato)dioxido-vanadium(V).

作者信息

Wang Chen-Yi, Wu Xiang, Cao Feng, Yuan Cai-Jun

机构信息

Department of Chemistry, Huzhou University, Huzhou 313000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1330. doi: 10.1107/S1600536811035240. Epub 2011 Sep 14.

DOI:10.1107/S1600536811035240
PMID:22065600
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3201471/
Abstract

In the title mononuclear dioxidovanadium(V) complex, [V(C(13)H(16)BrN(2)O(2))O(2)], the V(V) atom is five-coordinated by one phenolate O, one imine N and one morpholine N atom of the Schiff base ligand, and by two oxide O atoms, forming a distorted square-pyramidal geometry. In the crystal, weak C-H⋯O inter-actions and a short Br⋯Br contact [3.4597 (12) Å] are observed.

摘要

在标题单核二氧化钒（V）配合物[V(C₁₃H₁₆BrN₂O₂)O₂]中，V(V)原子由席夫碱配体的一个酚氧原子、一个亚胺氮原子和一个吗啉氮原子以及两个氧原子五配位，形成扭曲的四方锥几何构型。在晶体中，观察到弱的C—H⋯O相互作用和短的Br⋯Br接触[3.4597 (12) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b98d/3201471/ec4a6be3ea36/e-67-m1330-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b98d/3201471/ec4a6be3ea36/e-67-m1330-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b98d/3201471/ec4a6be3ea36/e-67-m1330-fig1.jpg

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本文引用的文献

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