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室内外空气中萘的来源、浓度和风险。

Sources, concentrations, and risks of naphthalene in indoor and outdoor air.

机构信息

University of Michigan, Ann Arbor, MI 48109-2029, USA.

出版信息

Indoor Air. 2012 Aug;22(4):266-78. doi: 10.1111/j.1600-0668.2011.00760.x. Epub 2012 Jan 11.

Abstract

UNLABELLED

Naphthalene is a ubiquitous pollutant, and very high concentrations are sometimes encountered indoors when this chemical is used as a pest repellent or deodorant. This study describes the distribution and sources of vapor-phase naphthalene concentrations in four communities in southeast Michigan, USA. Outdoors, naphthalene was measured in the communities and at a near-road site. Indoors, naphthalene levels were characterized in 288 suburban and urban homes. The median outdoor concentration was 0.15 μg/m(3), and a modest contribution from rush-hour traffic was noted. The median indoor long-term concentration was 0.89 μg/m(3), but concentrations were extremely skewed and 14% of homes exceeded 3 μg/m(3), the chronic reference concentration for non-cancer effects, 8% exceeded 10 μg/m(3), and levels reached 200 μg/m(3). The typical excess individual lifetime cancer risk was about 10(-4) and reached 10(-2) in some homes. Important sources include naphthalene's use as a pest repellent and deodorant, migration from attached garages and, to lesser extents, cigarette smoke and vehicle emissions. Excessive use as a repellent caused the highest concentrations. Naphthalene presents high risks in a subset of homes, and policies and actions to reduce exposures, for example, sales bans or restrictions, improved labeling, and consumer education, should be considered.

PRACTICAL IMPLICATIONS

Long-term average concentrations of naphthalene in most homes fell into the 0.2-1.7 μg/m(3) range reported as representative in earlier studies. The highly skewed distribution of concentrations results in a subset of homes with elevated concentrations and health risks that greatly exceed US EPA and World Health Organization (WHO) guidelines. The most important indoor source is the use of naphthalene as a pest repellant or deodorant; secondary sources include presence of an attached garage, cigarette smoking, and outdoor sources. House-to-house variation was large, reflecting differences among the residences and naphthalene use practices. Stronger policies and educational efforts are needed to eliminate or modify indoor usage practices of this chemical.

摘要

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萘是一种无处不在的污染物,当这种化学物质被用作驱虫剂或除臭剂时,室内有时会遇到非常高的浓度。本研究描述了美国密歇根州东南部四个社区中气相萘浓度的分布和来源。在户外,在社区和靠近道路的地方测量了萘的浓度。在室内,对 288 个郊区和城市住宅中的萘水平进行了描述。室外空气中的中位数浓度为 0.15μg/m(3),并注意到高峰时段交通的适度贡献。室内长期平均浓度中位数为 0.89μg/m(3),但浓度非常偏斜,14%的家庭超过 3μg/m(3),即非癌症影响的慢性参考浓度,8%的家庭超过 10μg/m(3),浓度达到 200μg/m(3)。典型的个体超额终生癌症风险约为 10(-4),在一些家庭中达到 10(-2)。重要来源包括萘作为驱虫剂和除臭剂的使用、从附接的车库迁移,以及在较小程度上,香烟烟雾和车辆排放。作为驱虫剂的过度使用导致了最高浓度。萘在一部分家庭中存在高风险,应考虑采取政策和行动来减少暴露,例如销售禁令或限制、改进标签和消费者教育。

实际意义

大多数家庭中萘的长期平均浓度处于之前研究报告的 0.2-1.7μg/m(3)代表性范围内。浓度的高度偏斜分布导致一部分家庭的浓度和健康风险大大超过美国环保署和世界卫生组织(WHO)的指导方针。最重要的室内来源是使用萘作为驱虫剂或除臭剂;次要来源包括附接的车库、吸烟和室外来源。家庭间的差异很大,反映了住宅和萘使用习惯的差异。需要采取更强有力的政策和教育努力来消除或修改这种化学物质的室内使用习惯。

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