Nalbach P, Braun D, Thorwart M
I. Institut für Theoretische Physik, Universität Hamburg, Jungiusstraße 9, D-20355 Hamburg, Germany.
Phys Rev E Stat Nonlin Soft Matter Phys. 2011 Oct;84(4 Pt 1):041926. doi: 10.1103/PhysRevE.84.041926. Epub 2011 Oct 21.
We present numerically exact results for the quantum coherent energy transfer in the Fenna-Matthews-Olson molecular aggregate under realistic physiological conditions, including vibrational fluctuations of the protein and the pigments for an experimentally determined fluctuation spectrum. We find coherence times shorter than observed experimentally. Furthermore, we determine the energy transfer current and quantify its "quantumness" as the distance of the density matrix to the classical pointer states for the energy current operator. Most importantly, we find that the energy transfer happens through a "Schrödinger-cat-like" superposition of energy current pointer states.
我们给出了在实际生理条件下,费纳 - 马修斯 - 奥尔森分子聚集体中量子相干能量转移的数值精确结果,包括蛋白质和色素的振动涨落,其涨落谱由实验确定。我们发现相干时间比实验观测到的要短。此外,我们确定了能量转移电流,并将其“量子性”量化为能量电流算符的密度矩阵到经典指针态的距离。最重要的是,我们发现能量转移通过能量电流指针态的“类薛定谔猫”叠加发生。