Brønsted acid catalyzed asymmetric propargylation of aldehydes.
作者信息
Jain Pankaj, Wang Hao, Houk Kendall N, Antilla Jon C
机构信息
Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620, USA.
出版信息
Angew Chem Int Ed Engl. 2012 Feb 6;51(6):1391-4. doi: 10.1002/anie.201107407. Epub 2011 Dec 28.
Abstract
摘要
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本文引用的文献
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Catalytic Asymmetric Allenylation: Regulation of the Equilibrium between Propargyl- and Allenylstannanes during the Catalytic Process.催化不对称烯丙基化：催化过程中炔丙基锡烷和烯丙基锡烷之间平衡的调控
Angew Chem Int Ed Engl. 1998 Sep 18;37(17):2392-2395. doi: 10.1002/(SICI)1521-3773(19980918)37:17<2392::AID-ANIE2392>3.0.CO;2-D.
2
Chiral allenylboronic esters as practical reagents for enantioselective carbon-carbon bond formation. Facile synthesis of (-)-ipsenol.手性联烯硼酸酯作为对映选择性碳-碳键形成的实用试剂。（-）-异松油烯醇的简便合成。
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Asymmetric reduction of ketones by phosphoric acid derived catalysts.磷酸衍生催化剂催化酮的不对称还原反应
Angew Chem Int Ed Engl. 2011 Nov 11;50(46):10961-4. doi: 10.1002/anie.201103883. Epub 2011 Sep 22.
4
Asymmetric propargylation of ketones using allenylboronates catalyzed by chiral biphenols.手性联苯酚催化烯丙基硼酸酯不对称炔丙基化反应。
Org Lett. 2011 Aug 5;13(15):4020-3. doi: 10.1021/ol201535b. Epub 2011 Jul 6.
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Ligand-accelerated enantioselective propargylation of aldehydes via allenylzinc reagents.通过烯丙基锌试剂实现配体加速的醛的对映选择性炔丙基化反应。
Org Lett. 2011 Apr 15;13(8):1900-3. doi: 10.1021/ol200043n. Epub 2011 Mar 10.
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Helical chiral 2,2'-bipyridine N-monoxides as catalysts in the enantioselective propargylation of aldehydes with allenyltrichlorosilane.手性 2,2'-联吡啶 N-单氧化物作为催化剂在手性选择性丙炔基化醛与烯丙基三氯硅烷反应中的应用。
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Catalytic asymmetric propargylation.催化不对称炔丙基化反应
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8
Asymmetric Nozaki-Hiyama propargylation of aldehydes: enhancement of enantioselectivity by cobalt co-catalysis.醛的不对称野崎-桧山炔丙基化反应：钴共催化提高对映选择性
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Synthesis of (-)-sedinine by allene cyclization and iminium ion chemistry.通过丙二烯环化和亚胺离子化学合成（-）-西丁宁。
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