无过渡金属参与的、可循环使用的多相催化剂作用下芳基卤代烃对未活化芳烃的高化学选择性和区域选择性芳基化反应。
Transition-metal-free highly chemo- and regioselective arylation of unactivated arenes with aryl halides over recyclable heterogeneous catalysts.
机构信息
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.
出版信息
Chem Commun (Camb). 2012 Feb 14;48(14):2033-5. doi: 10.1039/c2cc16790e. Epub 2012 Jan 9.
PMID:22227601
Abstract
A novel heterogeneous catalysis system using metal-organic frameworks as catalyst demonstrated excellent chemo- and regioselectivity for the direct arylation of unactivated arenes with aryl iodides/bromides without the assistance of any transition metals.
摘要
一种新型的多相催化体系，使用金属有机骨架作为催化剂，在没有任何过渡金属的协助下，对未活化的芳基碘化物/溴化物进行直接芳基化反应，表现出优异的化学和区域选择性。
Zotero 插件