关于糖苷化反应中的所谓“动力学非端基效应”。
On a so-called "kinetic anomeric effect" in chemical glycosylation.
出版信息
Org Biomol Chem. 2012 Apr 7;10(13):2503-8. doi: 10.1039/c2ob06696c. Epub 2012 Feb 16.
PMID:22336963
Abstract
Commentary on diastereoselectivity in chemical glycosylation reactions, and dismissal of the influence of stereoelectronic effects analogous to the anomeric effect in kinetically controlled reactions.
摘要
关于糖苷化反应中立体选择性的评论，以及排除类似动力学控制反应中端基效应的立体电子效应的影响。
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