Center for Soft Matter Research, Department of Physics, New York University, New York, NY 10003, USA.
Proc Natl Acad Sci U S A. 2012 Mar 27;109(13):4798-803. doi: 10.1073/pnas.1120215109. Epub 2012 Mar 5.
While the rheology of non-brownian suspensions in the dilute regime is well understood, their behavior in the dense limit remains mystifying. As the packing fraction of particles increases, particle motion becomes more collective, leading to a growing length scale and scaling properties in the rheology as the material approaches the jamming transition. There is no accepted microscopic description of this phenomenon. However, in recent years it has been understood that the elasticity of simple amorphous solids is governed by a critical point, the unjamming transition where the pressure vanishes, and where elastic properties display scaling and a diverging length scale. The correspondence between these two transitions is at present unclear. Here we show that for a simple model of dense flow, which we argue captures the essential physics near the jamming threshold, a formal analogy can be made between the rheology of the flow and the elasticity of simple networks. This analogy leads to a new conceptual framework to relate microscopic structure to rheology. It enables us to define and compute numerically normal modes and a density of states. We find striking similarities between the density of states in flow, and that of amorphous solids near unjamming: both display a plateau above some frequency scale ω(∗) ∼ |z(c) - z|, where z is the coordination of the network of particle in contact, z(c) = 2D where D is the spatial dimension. However, a spectacular difference appears: the density of states in flow displays a single mode at another frequency scale ω(min) ≪ ω(∗) governing the divergence of the viscosity.
虽然非布朗悬浮液在稀相状态下的流变学已经得到很好的理解,但它们在密集状态下的行为仍然令人费解。随着颗粒堆积分数的增加,颗粒运动变得更加集体化,导致流变学中的长度尺度不断增加,并且在材料接近堆积转变时呈现出标度特性。目前还没有对此现象的公认微观描述。然而,近年来人们已经理解,简单非晶固体的弹性由临界点决定,即在无压力的情况下发生脱黏转变,弹性特性显示出标度和发散长度尺度。目前这两个转变之间的对应关系尚不清楚。在这里,我们展示了对于一种简单的密集流动模型,我们认为它在堆积转变附近捕捉到了基本物理特性,流动的流变学和简单网络的弹性之间可以建立形式上的类比。这种类比为将微观结构与流变学联系起来提供了一个新的概念框架。它使我们能够定义和数值计算正常模式和态密度。我们发现流动中的态密度与无黏结附近的非晶固体之间存在惊人的相似之处:两者都在某个频率尺度 ω(∗) ∼ |z(c) - z|之上显示出一个平台,其中 z 是接触颗粒的网络的配位数,z(c) = 2D,其中 D 是空间维度。然而,出现了一个惊人的差异:流动中的态密度在另一个频率尺度 ω(min) ≪ ω(∗)下显示出一个主导粘度发散的单一模式。