镁催化的醛酮的硼氢化反应。
Magnesium-catalysed hydroboration of aldehydes and ketones.
机构信息
Department of Chemistry, University of Bath, Claverton down, Bath, BA2 7AY, UK.
出版信息
Chem Commun (Camb). 2012 May 14;48(38):4567-9. doi: 10.1039/c2cc30565h. Epub 2012 Apr 4.
PMID:22473045
Abstract
The heteroleptic magnesium alkyl complex [CH{C(Me)NAr}(2)Mg(n)Bu] (Ar = 2,6-(i)Pr(2)C(6)H(3)) is reported as a highly efficient pre-catalyst for the hydroboration of aldehydes and ketones with pinacolborane.
摘要
报道了一种手性镁烷基配合物 [CH{C(Me)NAr}(2)Mg(n)Bu]（Ar = 2,6-（i）Pr(2)C(6)H(3)），它是一种高效的前催化剂，可用于醛和酮与频哪醇硼烷的氢硼化反应。
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