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经济、绿色的荧光碳纳米粒子合成及其作为灵敏和选择性检测汞(II)离子探针的应用。

Economical, green synthesis of fluorescent carbon nanoparticles and their use as probes for sensitive and selective detection of mercury(II) ions.

机构信息

State Key Lab of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, P. R. China.

出版信息

Anal Chem. 2012 Jun 19;84(12):5351-7. doi: 10.1021/ac3007939. Epub 2012 Jun 11.

Abstract

The present article reports on a simple, economical, and green preparative strategy toward water-soluble, fluorescent carbon nanoparticles (CPs) with a quantum yield of approximately 6.9% by hydrothermal process using low cost wastes of pomelo peel as a carbon source for the first time. We further explore the use of such CPs as probes for a fluorescent Hg(2+) detection application, which is based on Hg(2+)-induced fluorescence quenching of CPs. This sensing system exhibits excellent sensitivity and selectivity toward Hg(2+), and a detection limit as low as 0.23 nM is achieved. The practical use of this system for Hg(2+) determination in lake water samples is also demonstrated successfully.

摘要

本文首次报道了一种简单、经济、绿色的水相制备策略,通过水热法以柚子皮这种廉价的废料为碳源,制备出具有约 6.9%量子产率的水溶性荧光碳纳米粒子(CPs)。我们进一步探索了将这些 CPs 用作荧光 Hg(2+)检测应用的探针,这是基于 CPs 被 Hg(2+)诱导荧光猝灭。该传感体系对 Hg(2+)具有优异的灵敏度和选择性,检测限低至 0.23 nM。该系统还成功地用于实际湖水样品中 Hg(2+)的测定。

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