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采用气相色谱和手性气相色谱-质谱法对乳香和卡氏乳香精油进行化学鉴别。

Chemical differentiation of Boswellia sacra and Boswellia carterii essential oils by gas chromatography and chiral gas chromatography-mass spectrometry.

机构信息

Department of Research and Discovery, Young Living Essential Oils, 3125 W, Executive Pkwy, Lehi, UT, USA.

出版信息

J Chromatogr A. 2012 Oct 26;1261:158-63. doi: 10.1016/j.chroma.2012.06.073. Epub 2012 Jun 28.

Abstract

Major botanical and scientific references currently identify two species of frankincense, Boswellia carterii and Boswellia sacra, as being synonymous. We evaluated the Somalian (B. carterii) and Omani/Yemeni (B. sacra) species by chemical analyses to determine if there were any minor or major differences between the two species of frankincense. Components identified with their average percent for B. sacra are α-thujene (0.6%), α-pinene (68.2%), camphene (2.1%), sabinene (2.9%), β-pinene (2.0%), myrcene (0.7%), limonene+β-phellandrene (6.2%). Components identified with their average percent for B. carterii are α-thujene (7.9%), α-pinene (37.3%), camphene (0.8%), sabinene (4.9%), β-pinene (1.8%), myrcene (7.3%), limonene+β-phellandrene (14.4%). Initially, GC-MS analysis did not reveal major statistical differences. However, optical rotation values, B. Sacra (+30.1°) and B. carterii (-13.3°), demonstrated a greater significant difference. Enantiomeric ratio (+)/(-) values of α-pinene for B. sacra and B. carterii are 8.24 and 0.68, respectively, were also calculated aiding our conclusion that B. sacra and B. carterii are not synonymous but rather two distinct and individual frankincense species.

摘要

目前主要的植物学和科学参考文献将乳香的两个物种,即 Boswellia carterii 和 Boswellia sacra,鉴定为同义词。我们通过化学分析评估了索马里(B. carterii)和阿曼/也门(B. sacra)物种,以确定这两种乳香之间是否存在任何次要或主要差异。用其平均百分比鉴定出的成分 B. sacra 是 α-蒎烯(0.6%)、α-蒎烯(68.2%)、莰烯(2.1%)、月桂烯(2.9%)、β-蒎烯(2.0%)、苎烯(0.7%)、柠檬烯+β-水芹烯(6.2%)。用其平均百分比鉴定出的成分 B. carterii 是 α-蒎烯(7.9%)、α-蒎烯(37.3%)、莰烯(0.8%)、月桂烯(4.9%)、β-蒎烯(1.8%)、苎烯(7.3%)、柠檬烯+β-水芹烯(14.4%)。最初,GC-MS 分析并未显示出主要的统计差异。然而,旋光值 B. Sacra(+30.1°)和 B. carterii(-13.3°)显示出更大的显著差异。B. sacra 和 B. carterii 的 α-蒎烯对映体比(+)/(-)值分别为 8.24 和 0.68,这也有助于我们得出结论,即 B. sacra 和 B. carterii 不是同义词,而是两种不同的、独特的乳香物种。

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