Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen, Germany.
Angew Chem Int Ed Engl. 2012 Sep 17;51(38):9492-510. doi: 10.1002/anie.201202750. Epub 2012 Aug 21.
Polyoxometalates containing noble metal ions, such as ruthenium, osmium, rhodium, palladium, platinum, silver and gold, are a structurally diverse class of compounds. They include both classical heteropolyanions (vanadates, molybdates, tungstates) in which noble metals are present as heteroatoms, as well as the recently discovered class of polyoxometalates with noble metal "addenda" atoms. The focus of this Review is on complexes that should, in principle, exist as discrete molecular species in solution, and which are therefore of interest for their reactivity, their future synthetic utility and potential applications, for example, in catalysis or nanoscience.
含贵金属离子（如钌、锇、铑、钯、铂、银和金）的多金属氧酸盐是一类结构多样的化合物。它们既包括经典的杂多阴离子（钒酸盐、钼酸盐、钨酸盐），其中贵金属作为杂原子存在，也包括最近发现的具有贵金属“附加原子”的多金属氧酸盐类。这篇综述的重点是那些原则上应该以离散的分子物种存在于溶液中的配合物，因此它们的反应性、未来的合成用途和潜在应用（例如在催化或纳米科学中的应用）引起了人们的兴趣。
