Faculty of Physics, Mahalingam College of Engineering and Technology, Pollachi, Tamilnadu, India.
ACS Appl Mater Interfaces. 2012 Sep 26;4(9):4484-90. doi: 10.1021/am301162p. Epub 2012 Sep 4.
Vanadium pentoxide (V(2)O(5)) has attracted attention for supercapcitor applications because of its extensive multifunctional properties. In the present study, V(2)O(5) nanoporous network was synthesized via simple capping-agent-assisted precipitation technique and it is further annealed at different temperatures. The effect of annealing temperature on the morphology, electrochemical and structural properties, and stability upon oxidation-reduction cycling has been analyzed for supercapacitor application. We achieved highest specific capacitance of 316 F g(-1) for interconnected V(2)O(5) nanoporous network. This interconnected nanoporous network creates facile nanochannels for ion diffusion and facilitates the easy accessibility of ions. Moreover, after six hundred consecutive cycling processes the specific capacitance has changed only by 24%. A simple cost-effective preparation technique of V(2)O(5) nanoporous network with excellent capacitive behavior, energy density, and stability encourages its possible commercial exploitation for the development of high-performance supercapacitors.
五氧化二钒(V(2)O(5))因其广泛的多功能特性而引起了超级电容器应用的关注。在本研究中,通过简单的封端剂辅助沉淀技术合成了 V(2)O(5)纳米多孔网络,并进一步在不同温度下进行退火。分析了退火温度对超级电容器应用的形态、电化学和结构性能以及氧化还原循环稳定性的影响。我们实现了互连的 V(2)O(5)纳米多孔网络的最高比电容为 316 F g(-1)。这种互连的纳米多孔网络为离子扩散创造了方便的纳米通道,并便于离子的容易进入。此外,经过六百次连续循环过程后,比电容仅变化了 24%。具有优异电容性能、能量密度和稳定性的 V(2)O(5)纳米多孔网络的简单、经济高效的制备技术,鼓励其可能在高性能超级电容器的开发中得到商业应用。