Kurc Beata, Wysokowski Marcin, Rymaniak Łukasz, Lijewski Piotr, Piasecki Adam, Fuć Paweł
Institute of Chemistry and Electrochemistry, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, PL-60965 Poznan, Poland.
Institute of Chemical Technology and Engineering, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, PL-60965 Poznan, Poland.
Materials (Basel). 2020 Feb 24;13(4):1018. doi: 10.3390/ma13041018.
This work determines the effect of the addition of various amounts of vanadium oxide on the work of a cell built from a hybrid VO-TiO-rGO system in a lithium-ion cell. Moreover, a new method based on solvothermal chemistry is proposed for the creation of a new type of composite material combining reduced graphene, vanadium oxide and crystalline anatase. The satisfactory electrochemical properties of VxOy-TiO-rGO hybrids can be attributed to the perfect matching of the morphology and structure of VxOy-TiO and rGO. In addition, it is also responsible for the partial transfer of electrons from rGO to VxOy-TiO, which increases the synergistic interaction of the VxOy-TiO-rGO hybrid to the reversible storage of lithium. In addition a full cell was created LiFePO/VO-TiO-rGO. The cell showed good cyclability while providing a capacity of 120 mAh g-.
这项工作确定了添加不同量的氧化钒对由锂离子电池中的混合VO-TiO-rGO系统构建的电池性能的影响。此外,还提出了一种基于溶剂热化学的新方法,用于制备一种结合了还原石墨烯、氧化钒和结晶锐钛矿的新型复合材料。VxOy-TiO-rGO杂化物令人满意的电化学性能可归因于VxOy-TiO和rGO的形态和结构的完美匹配。此外,它还负责电子从rGO到VxOy-TiO的部分转移,这增加了VxOy-TiO-rGO杂化物对锂可逆存储的协同相互作用。此外,还制造了一个LiFePO/VO-TiO-rGO全电池。该电池在提供120 mAh g-的容量时表现出良好的循环性能。