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氧化钒添加对锂离子电池中TiO-rGO电极的物理化学性能稳定性及锂离子嵌入的影响

The Impact of the Vanadium Oxide Addition on the Physicochemical Performance Stability and Intercalation of Lithium Ions of the TiO-rGO-electrode in Lithium Ion Batteries.

作者信息

Kurc Beata, Wysokowski Marcin, Rymaniak Łukasz, Lijewski Piotr, Piasecki Adam, Fuć Paweł

机构信息

Institute of Chemistry and Electrochemistry, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, PL-60965 Poznan, Poland.

Institute of Chemical Technology and Engineering, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, PL-60965 Poznan, Poland.

出版信息

Materials (Basel). 2020 Feb 24;13(4):1018. doi: 10.3390/ma13041018.

Abstract

This work determines the effect of the addition of various amounts of vanadium oxide on the work of a cell built from a hybrid VO-TiO-rGO system in a lithium-ion cell. Moreover, a new method based on solvothermal chemistry is proposed for the creation of a new type of composite material combining reduced graphene, vanadium oxide and crystalline anatase. The satisfactory electrochemical properties of VxOy-TiO-rGO hybrids can be attributed to the perfect matching of the morphology and structure of VxOy-TiO and rGO. In addition, it is also responsible for the partial transfer of electrons from rGO to VxOy-TiO, which increases the synergistic interaction of the VxOy-TiO-rGO hybrid to the reversible storage of lithium. In addition a full cell was created LiFePO/VO-TiO-rGO. The cell showed good cyclability while providing a capacity of 120 mAh g-.

摘要

这项工作确定了添加不同量的氧化钒对由锂离子电池中的混合VO-TiO-rGO系统构建的电池性能的影响。此外,还提出了一种基于溶剂热化学的新方法,用于制备一种结合了还原石墨烯、氧化钒和结晶锐钛矿的新型复合材料。VxOy-TiO-rGO杂化物令人满意的电化学性能可归因于VxOy-TiO和rGO的形态和结构的完美匹配。此外,它还负责电子从rGO到VxOy-TiO的部分转移,这增加了VxOy-TiO-rGO杂化物对锂可逆存储的协同相互作用。此外,还制造了一个LiFePO/VO-TiO-rGO全电池。该电池在提供120 mAh g-的容量时表现出良好的循环性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4a9/7078604/0f51cbc074a6/materials-13-01018-g001.jpg

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