Pennington-Boggio Megan K, Conley Brian L, Williams Travis J
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, California 90089-1661.
J Organomet Chem. 2012 Oct 1;716:6-10. doi: 10.1016/j.jorganchem.2012.05.017. Epub 2012 May 25.
Ruthenium(III) chloride hydrate is a convenient catalyst for the addition of active methylene compounds to aryl alkynes. These reactions are rapid, operationally simple, and high yielding in cases. Most significantly, no precautions are required to exclude air or water from the reactions. All reagents are commercially available at reasonable prices, and the reactions can be conducted in disposable glassware with minimal solvent.
水合三氯化钌是一种用于将活性亚甲基化合物加成到芳基炔烃上的便捷催化剂。这些反应速度快，操作简单，在某些情况下产率很高。最重要的是，反应无需采取预防措施来排除空气或水。所有试剂均可从商业渠道以合理价格购得，并且反应可以在一次性玻璃器皿中使用最少的溶剂进行。
