Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6493, USA.
Phys Rev Lett. 2012 Jun 29;108(26):266602. doi: 10.1103/PhysRevLett.108.266602. Epub 2012 Jun 28.
Space-charge-limited currents are important in energy devices such as solar cells and light-emitting diodes, but the available theory from the 1950s finds it necessary to postulate defect states that are distributed in energy in order to match data. Here, we show that this postulate is not warranted. Instead, we demonstrate that dopants and the concomitant Frenkel effect, which have been neglected, control the shape of measured current-voltage characteristics. We also account for the observed peak in the noise power. The new theory can anchor efforts to develop experimental techniques to measure deep-trap levels.
空间电荷限制电流在能源设备(如太阳能电池和发光二极管)中很重要,但 20 世纪 50 年代的现有理论发现,为了匹配数据,有必要假设能量分布的缺陷态。在这里,我们表明这种假设是没有根据的。相反,我们证明了被忽视的掺杂剂和伴生的弗伦克尔效应控制着测量电流-电压特性的形状。我们还解释了观察到的噪声功率峰值。新理论可以为开发测量深陷阱能级的实验技术提供依据。