Institute of Biotechnology and Pharmaceutical Research, National Health Research Institutes, Miaoli County 35053, Taiwan.
Molecules. 2012 Nov 20;17(11):13662-72. doi: 10.3390/molecules171113662.
Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.
在室温下,用二氯苯基膦(PhOP=OCl(2))在乙腈中处理时,各种酮肟以有效的方式经历贝克曼重排,以中等至高收率得到相应的酰胺。