长程阴离子接力化学（LR-ARC）：一种经过验证的 ARC 策略。
Long-range anion relay chemistry (LR-ARC): a validated ARC tactic.
机构信息
Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
出版信息
Org Lett. 2012 Dec 21;14(24):6314-7. doi: 10.1021/ol303080h. Epub 2012 Dec 6.
Abstract
The design, synthesis, and validation of linchpins for Anion Relay Chemistry (ARC) capable of iterative silyl group migrations have been achieved. This tactic permits "long-range" relocation of negative charge across space, to generate reactive distal nucleophilic centers for both alkylation and palladium-catalyzed coupling reactions.
摘要
已设计、合成并验证了能够进行迭代硅基迁移的阴离子接力化学（ARC）的关键中间体。这种策略允许负电荷在空间中“远程”迁移，从而生成用于烷基化和钯催化偶联反应的反应性远程亲核中心。
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