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白炽灯泡、紧凑型荧光灯(CFL)和发光二极管(LED)灯泡中金属的潜在环境影响。

Potential environmental impacts from the metals in incandescent, compact fluorescent lamp (CFL), and light-emitting diode (LED) bulbs.

机构信息

Department of Environmental Engineering, College of Engineering, Kangwon National University, Chuncheon, Gangwon 200-701, South Korea.

出版信息

Environ Sci Technol. 2013 Jan 15;47(2):1040-7. doi: 10.1021/es302886m. Epub 2012 Dec 28.

Abstract

Artificial lighting systems are transitioning from incandescent to compact fluorescent lamp (CFL) and light-emitting diode (LED) bulbs in response to the U.S. Energy Independence and Security Act and the EU Ecodesign Directive, which leads to energy savings and reduced greenhouse gas emissions. Although CFLs and LEDs are more energy-efficient than incandescent bulbs, they require more metal-containing components. There is uncertainty about the potential environmental impacts of these components and whether special provisions must be made for their disposal at the end of useful life. Therefore, the objective of this study is to analyze the resource depletion and toxicity potentials from the metals in incandescent, CFL, and LED bulbs to complement the development of sustainable energy policy. We assessed the potentials by examining whether the lighting products are to be categorized as hazardous waste under existing U.S. federal and California state regulations and by applying life cycle impact-based and hazard-based assessment methods (note that "life cycle impact-based method" does not mean a general life cycle assessment (LCA) but rather the elements in LCA used to quantify toxicity potentials). We discovered that both CFL and LED bulbs are categorized as hazardous, due to excessive levels of lead (Pb) leachability (132 and 44 mg/L, respectively; regulatory limit: 5) and the high contents of copper (111,000 and 31,600 mg/kg, respectively; limit: 2500), lead (3860 mg/kg for the CFL bulb; limit: 1000), and zinc (34,500 mg/kg for the CFL bulb; limit: 5000), while the incandescent bulb is not hazardous (note that the results for CFL bulbs excluded mercury vapor not captured during sample preparation). The CFLs and LEDs have higher resource depletion and toxicity potentials than the incandescent bulb due primarily to their high aluminum, copper, gold, lead, silver, and zinc. Comparing the bulbs on an equivalent quantity basis with respect to the expected lifetimes of the bulbs, the CFLs and LEDs have 3-26 and 2-3 times higher potential impacts than the incandescent bulb, respectively. We conclude that in addition to enhancing energy efficiency, conservation and sustainability policies should focus on the development of technologies that reduce the content of hazardous and rare metals in lighting products without compromising their performance and useful lifespan.

摘要

人工照明系统正在从白炽灯泡过渡到紧凑型荧光灯 (CFL) 和发光二极管 (LED) 灯泡,以响应美国的《能源独立和安全法案》和欧盟的《生态设计指令》,这将带来能源节约和温室气体排放减少。虽然 CFL 和 LED 比白炽灯泡更节能,但它们需要更多含金属的组件。对于这些组件的潜在环境影响以及它们在使用寿命结束时是否必须采取特殊处置措施存在不确定性。因此,本研究的目的是分析白炽灯泡、CFL 和 LED 灯泡中金属的资源枯竭和毒性潜力,以补充可持续能源政策的制定。我们通过检查照明产品是否根据现有的美国联邦和加利福尼亚州法规被归类为危险废物来评估这些潜力,同时应用基于生命周期影响的和基于危害的评估方法(请注意,“基于生命周期影响的方法”并非指一般性的生命周期评估 (LCA),而是 LCA 中用于量化毒性潜力的要素)。我们发现,由于 Pb 的浸出率过高(分别为 132 和 44mg/L,法规限制为 5)以及铜(分别为 111,000 和 31,600mg/kg,限制为 2500)、铅(CFL 灯泡为 3860mg/kg;限制为 1000)和锌(CFL 灯泡为 34,500mg/kg;限制为 5000)含量过高,CFL 和 LED 灯泡均被归类为危险废物,而白炽灯泡则不是危险废物(请注意,CFL 灯泡的结果排除了在样品制备过程中未捕获的汞蒸气)。由于其高含量的铝、铜、金、铅、银和锌,CFL 和 LED 比白炽灯泡具有更高的资源枯竭和毒性潜力。在考虑到灯泡预期寿命的基础上,以相同数量为基准进行比较,CFL 和 LED 灯泡的潜在影响分别比白炽灯泡高出 3-26 倍和 2-3 倍。我们的结论是,除了提高能源效率之外,保护和可持续性政策还应侧重于开发减少照明产品中危险和稀有金属含量的技术,而不会影响其性能和有用寿命。

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