Anhui Province Key Laboratory of Biomass Clean Energy, Department of Chemistry, University of Science and Technology of China, Hefei 230026, PR China.
ChemSusChem. 2013 Jan;6(1):47-50. doi: 10.1002/cssc.201200652. Epub 2012 Dec 13.
One divided into two combined into one: The catalytic conversion of furfural into a 2,5-furandicarboxylic acid-based polyester, linked by the disproportionation of furoate to furan and 2,5-furandicarboxylate, is reported. In this manner, all carbons are utilized, demonstrating the success of combining a platform molecule from C(5) sugars (furfural) to one from C(6) sugars (2,5-FDCA).
一分为二，合二为一：通过呋喃酸盐歧化生成呋喃和 2,5-呋喃二甲酸酯，将糠醛转化为基于 2,5-呋喃二甲酸的聚酯的催化转化被报道。通过这种方式，所有的碳都被利用，证明了将 C(5)糖（糠醛）的平台分子与 C(6)糖（2,5-FDCA）结合的成功。
