糠醛到基于 2,5-呋喃二甲酸的聚酯的催化转化实现总碳利用。
Catalytic conversion of furfural into a 2,5-furandicarboxylic acid-based polyester with total carbon utilization.
机构信息
Anhui Province Key Laboratory of Biomass Clean Energy, Department of Chemistry, University of Science and Technology of China, Hefei 230026, PR China.
出版信息
ChemSusChem. 2013 Jan;6(1):47-50. doi: 10.1002/cssc.201200652. Epub 2012 Dec 13.
PMID:23239596
Abstract
One divided into two combined into one: The catalytic conversion of furfural into a 2,5-furandicarboxylic acid-based polyester, linked by the disproportionation of furoate to furan and 2,5-furandicarboxylate, is reported. In this manner, all carbons are utilized, demonstrating the success of combining a platform molecule from C(5) sugars (furfural) to one from C(6) sugars (2,5-FDCA).
摘要
一分为二，合二为一：通过呋喃酸盐歧化生成呋喃和 2,5-呋喃二甲酸酯，将糠醛转化为基于 2,5-呋喃二甲酸的聚酯的催化转化被报道。通过这种方式，所有的碳都被利用，证明了将 C(5)糖（糠醛）的平台分子与 C(6)糖（2,5-FDCA）结合的成功。
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