Clean Fuel Department, High Efficiency and Clean Energy Research Division, Korea Institute of Energy Research (KIER), 71-2, Jang-dong, Yuseong, Daejeon 305-343, Republic of Korea.
Environ Sci Technol. 2013 Feb 5;47(3):1704-10. doi: 10.1021/es303341j. Epub 2013 Jan 11.
Coal-fired power plants are facing to two major independent problems, namely, the burden to reduce CO(2) emission to comply with renewable portfolio standard (RPS) and cap-and-trade system, and the need to use low-rank coal due to the instability of high-rank coal supply. To address such unresolved issues, integrated gasification combined cycle (IGCC) with carbon capture and storage (CCS) has been suggested, and low rank coal has been upgraded by high-pressure and high-temperature processes. However, IGCC incurs huge construction costs, and the coal upgrading processes require fossil-fuel-derived additives and harsh operation condition. Here, we first show a hybrid coal that can solve these two problems simultaneously while using existing power plants. Hybrid coal is defined as a two-in-one fuel combining low rank coal with a sugar cane-derived bioliquid, such as molasses and sugar cane juice, by bioliquid diffusion into coal intrapores and precarbonization of the bioliquid. Unlike the simple blend of biomass and coal showing dual combustion behavior, hybrid coal provided a single coal combustion pattern. If hybrid coal (biomass/coal ratio = 28 wt %) is used as a fuel for 500 MW power generation, the net CO(2) emission is 21.2-33.1% and 12.5-25.7% lower than those for low rank coal and designed coal, and the required coal supply can be reduced by 33% compared with low rank coal. Considering high oil prices and time required before a stable renewable energy supply can be established, hybrid coal could be recognized as an innovative low-carbon-emission energy technology that can bridge the gulf between fossil fuels and renewable energy, because various water-soluble biomass could be used as an additive for hybrid coal through proper modification of preparation conditions.
燃煤电厂面临着两个相互独立的问题,即需要降低 CO(2)排放以符合可再生能源组合标准 (RPS) 和总量管制与排放交易制度,以及由于高品位煤供应不稳定而需要使用低品位煤。为了解决这些未解决的问题,已经提出了集成煤气化联合循环(IGCC)与碳捕集和封存(CCS),并且已经通过高压高温工艺对低品位煤进行了升级。然而,IGCC 会产生巨大的建设成本,而煤炭升级工艺需要化石燃料衍生的添加剂和苛刻的操作条件。在这里,我们首先展示了一种可以同时解决这两个问题的混合煤,同时使用现有的发电厂。混合煤被定义为一种将低品位煤与甘蔗衍生的生物液体(如糖蜜和甘蔗汁)结合在一起的二合一燃料,通过生物液体扩散到煤的内孔和生物液体的预碳化。与表现出双重燃烧行为的生物质和煤的简单混合物不同,混合煤提供了单一的煤燃烧模式。如果将混合煤(生物质/煤的比例为 28wt%)用作 500MW 发电的燃料,则净 CO(2)排放比低品位煤和设计煤分别低 21.2-33.1%和 12.5-25.7%,与低品位煤相比,所需的煤炭供应可减少 33%。考虑到高油价和稳定可再生能源供应建立所需的时间,混合煤可以被认为是一种创新的低碳排放能源技术,可以弥合化石燃料和可再生能源之间的差距,因为通过适当修改制备条件,可以将各种水溶性生物质用作混合煤的添加剂。