Department of Chemistry, Southern Methodist University, 3215 Daniel Avenue, Dallas, TX 75275-0314, USA.
Chem Soc Rev. 2013 Sep 7;42(17):7214-43. doi: 10.1039/c3cs35499g. Epub 2013 Feb 28.
Interest in thermoresponsive polymers has steadily grown over many decades, and a great deal of work has been dedicated to developing temperature sensitive macromolecules that can be crafted into new smart materials. However, the overwhelming majority of previously reported temperature-responsive polymers are based on poly(N-isopropylacrylamide) (PNIPAM), despite the fact that a wide range of other thermoresponsive polymers have demonstrated similar promise for the preparation of adaptive materials. Herein, we aim to highlight recent results that involve thermoresponsive systems that have not yet been as fully considered. Many of these (co)polymers represent clear opportunities for advancements in emerging biomedical and materials fields due to their increased biocompatibility and tuneable response. By highlighting recent examples of newly developed thermoresponsive polymer systems, we hope to promote the development of new generations of smart materials.
几十年来，人们对温敏聚合物的兴趣稳步增长，大量的工作致力于开发温度敏感的高分子聚合物，以制成新型智能材料。然而，尽管有许多其他温敏聚合物在制备自适应材料方面显示出了类似的前景，但之前报道的绝大多数温度响应聚合物都基于聚(N-异丙基丙烯酰胺)(PNIPAM)。本文旨在强调最近涉及尚未得到充分考虑的温敏体系的研究结果。由于这些（共）聚合物具有更高的生物相容性和可调的响应，它们为新兴的生物医学和材料领域的发展提供了很多机会。通过强调新开发的温敏聚合物体系的最新实例，我们希望推动新一代智能材料的发展。
