Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron-substituted allylcopper complexes and their in situ site-, diastereo-, and enantioselective additions to aldehydes and ketones.
作者信息
Meng Fanke, Jang Hwanjong, Jung Byunghyuck, Hoveyda Amir H
机构信息
Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467, USA.
出版信息
Angew Chem Int Ed Engl. 2013 May 3;52(19):5046-51. doi: 10.1002/anie.201301018. Epub 2013 Apr 3.
Abstract
摘要
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Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron-substituted allylcopper complexes and their in situ site-, diastereo-, and enantioselective additions to aldehydes and ketones.铜催化的2-(频哪醇硼酸酯)硼取代烯丙基铜配合物的化学选择性制备及其对醛和酮的原位位点、非对映体和对映体选择性加成反应。
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Highly diastereoselective construction of acyclic systems with two adjacent quaternary stereocenters by allylation of ketones.通过酮的烯丙基化反应高非对映选择性构建具有两个相邻季碳中心的非环体系。
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