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Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron-substituted allylcopper complexes and their in situ site-, diastereo-, and enantioselective additions to aldehydes and ketones.

作者信息

Meng Fanke, Jang Hwanjong, Jung Byunghyuck, Hoveyda Amir H

机构信息

Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467, USA.

出版信息

Angew Chem Int Ed Engl. 2013 May 3;52(19):5046-51. doi: 10.1002/anie.201301018. Epub 2013 Apr 3.

DOI:10.1002/anie.201301018
PMID:23553989
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3806314/
Abstract
摘要

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Palladium-catalyzed synthesis and isolation of functionalized allylboronic acids: selective, direct allylboration of ketones.钯催化合成和官能化烯丙基硼酸的分离：酮的选择性、直接烯丙基硼化。
Angew Chem Int Ed Engl. 2012 Dec 21;51(52):13050-3. doi: 10.1002/anie.201207951. Epub 2012 Nov 19.
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Highly diastereoselective construction of acyclic systems with two adjacent quaternary stereocenters by allylation of ketones.通过酮的烯丙基化反应高非对映选择性构建具有两个相邻季碳中心的非环体系。
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Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.铜催化的对映选择性烯丙基取代反应，使用易于获得的含羰基和缩醛的乙烯基硼试剂。
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Bis(allyl)zinc revisited: sigma versus pi bonding of allyl coordination.重新审视双(烯丙基)锌：烯丙基配位的 sigma 键与 pi 键。
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A unique approach to the concise synthesis of highly optically active spirooxazolines and the discovery of a more potent oxindole-type phytoalexin analogue.一种独特的方法，用于简洁合成高光学活性螺噁唑啉，并发现更有效的氧化吲哚型植物抗毒素类似物。
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