Department of Biomedical Engineering, College of Health Science, Korea University, Jeongeung-dong, Seongbuk-gu, Seoul, 136-703, Republic of Korea.
Adv Mater. 2013 Jun 11;25(22):3071-8. doi: 10.1002/adma.201300837. Epub 2013 Apr 25.
A new method for the microfluidic spinning of ultrathin fibers with highly ordered structures is proposed by mimicking the spinning mechanism of silkworms. The self-aggregation is driven by dipole-dipole attractions between polar polymers upon contact with a low-polarity solvent to form fibers with nanostrands. The induction of Kelvin-Helmholtz instabilities at the dehydrating interface between two miscible fluids generates multi-scale fibers in a single microchannel.
提出了一种模仿蚕茧纺丝机制的新方法,用于制备具有高度有序结构的超细微纤维。当与低极性溶剂接触时,极性聚合物之间的偶极-偶极吸引力会导致自组装,从而形成具有纳米原纤维的纤维。在两种可混溶流体的脱水界面处诱导开尔文-亥姆霍兹不稳定性,可以在单个微通道中生成多尺度纤维。