钌(II)催化的芳香酮与磺酰叠氮化物的分子间邻位 C-H 酰胺化反应。
Ru(II)-catalyzed intermolecular ortho-C-H amidation of aromatic ketones with sulfonyl azides.
机构信息
School of Chemistry, University of Hyderabad, Hyderabad 500046, India.
出版信息
Chem Commun (Camb). 2013 Jun 7;49(45):5225-7. doi: 10.1039/c3cc41915k.
PMID:23628894
Abstract
Ru(II)-catalyzed intermolecular ortho-C-H amidation of weakly coordinating aromatic ketones with sulfonyl azides is reported. The developed reaction protocol can be extended to various substituted aromatic ketones to afford a wide range of desired C-N bond formation products in good yields.
摘要
报道了 Ru(II)催化的弱配位芳基酮与磺酰基叠氮化物的分子间邻位 C-H 酰胺化反应。所开发的反应方案可以扩展到各种取代的芳基酮，以良好的收率得到广泛的所需 C-N 键形成产物。
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