不对称钯催化的不饱和醇和氨基醇的分子内 Wacker 型环化反应。
Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.
机构信息
Department of Organic Chemistry, Slovak University of Technology, Radlinského 9, SK-812 37 Bratislava, Slovakia.
出版信息
Molecules. 2013 May 24;18(6):6173-92. doi: 10.3390/molecules18066173.
Abstract
The palladium (II)-catalysed reactions of alkenols and aminoalkenols such as oxycarbonylations or bicyclisations are powerful methods for the construction of oxygen and nitrogen-containing heterocyclic compounds. This review highlights recent progress in the development of the asymmetric palladium(II)-catalysed Wacker-type cyclisations of unsaturated polyols and aminoalcohols. The scope, limitations, and applications of these reactions are presented.
摘要
钯（II）催化的烯醇和氨基烯醇的反应，如氧羰基化或双环化反应，是构建含氧和含氮杂环化合物的有力方法。本文综述了不饱和多元醇和氨基醇的不对称钯（II）催化瓦克型环化反应的最新进展。介绍了这些反应的范围、限制和应用。
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