College of Light Industry and Textile and Food Engineering, Sichuan University, Chengdu, Sichuan 610005, China.
Macromol Rapid Commun. 2013 Jul 25;34(14):1118-33. doi: 10.1002/marc.201300288. Epub 2013 May 31.
This Review focuses on the recent progress in the area of CO2 -responsive polymers and provides detailed descriptions of these existing examples. CO2 -responsive polymers can be categorized into three types based on their CO2 -responsive groups: amidine, amine, and carboxyl groups. Compared with traditional temperature, pH, or light stimuli-responsive polymers, CO2 -responsive polymers provide the advantage to use CO2 as a "green" trigger as well as to capture CO2 directly from air. In addition, the current challenges of CO2 -responsive polymers are discussed and the different solution methods are compared. Noteworthy, CO2 -responsive polymers are considered to have a prosperous future in various scientific areas.
这篇综述重点介绍了 CO2 响应性聚合物领域的最新进展,并详细描述了这些现有实例。根据其 CO2 响应基团,CO2 响应性聚合物可分为三类:脒基、氨基和羧基。与传统的温度、pH 值或光刺激响应性聚合物相比,CO2 响应性聚合物不仅提供了使用 CO2 作为“绿色”触发物的优势,还可以直接从空气中捕获 CO2。此外,还讨论了 CO2 响应性聚合物目前面临的挑战,并比较了不同的解决方案。值得注意的是,CO2 响应性聚合物被认为在各个科学领域具有广阔的前景。