Institut für Organische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig, Germany.
Chembiochem. 2013 Jul 8;14(10):1189-93. doi: 10.1002/cbic.201300254. Epub 2013 Jun 18.
Complex bouquet: A recently developed method for trace analyses combining the advantages of GC-MS and (13) C NMR spectroscopy was applied to investigate the volatiles of Penicillium roqueforti. Besides the main compound, aristolochene, several side products of aristolochene synthase and downstream oxidation products en route to PR toxin were identified, giving insight into the biosynthetic pathway.
最近开发的一种将 GC-MS 和(13)C NMR 光谱优势相结合的痕量分析方法被应用于研究罗伊氏青霉的挥发物。除了主化合物,阿里斯托烯,阿里斯托烯合酶的几个副产物和 PR 毒素下游氧化产物也被鉴定出来,这为生物合成途径提供了深入了解。