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无机和有机体系的机械化学:有何异同?

Mechanochemistry of inorganic and organic systems: what is similar, what is different?

机构信息

Institute of Solid State Chemistry and Mechanochemistry SB RAS, ul. Kutateladze, 18, Novosibirsk, Russia.

出版信息

Chem Soc Rev. 2013 Sep 21;42(18):7719-38. doi: 10.1039/c3cs60052a. Epub 2013 Jul 17.

Abstract

Mechanochemistry of inorganic solids is a well-established field. In the last decade mechanical treatment has become increasingly popular as a method for achieving selective and "greener" syntheses also in organic systems. New groups and researchers enter the field of mechanochemistry, often re-discovering many of the previously known facts and effects, while at the same time neglecting other important concepts. The author of this contribution has long been involved in mechanochemical research in both inorganic and organic systems. The aim of this contribution is to provide an overview of the basic concepts of mechanochemistry in relation to inorganic and organic systems.

摘要

无机固体的机械化学是一个成熟的领域。在过去的十年中,机械处理作为一种实现有机体系中选择性和“更绿色”合成的方法越来越受欢迎。新的团体和研究人员进入机械化学领域,经常重新发现许多以前已知的事实和效应,同时忽略了其他重要的概念。本文作者长期从事无机和有机体系的机械化学研究。本文的目的是提供一个关于无机和有机体系的机械化学基本概念的概述。

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